0001: SET sql_mode = ? 0.0004s

0002: SHOW DATABASES LIKE 'igi\_cms\_future' 0.003s

0003: SHOW TABLES LIKE 'SubsiteDomain' 0.0016s

0004: SELECT DISTINCT count(DISTINCT "SubsiteDomain"."ID") AS "Count" FROM "SubsiteDomain" INNER JOIN "Subsite" ON "Subsite"."ID" = "SubsiteDomain"."SubsiteID" AND "Subsite"."IsPublic"=1 WHERE ('igiltd.dev' LIKE replace("SubsiteDomain"."Domain",'*','%')) 0.0007s

0005: SELECT DISTINCT "Subsite"."ClassName", "Subsite"."LastEdited", "Subsite"."Created", "Subsite"."DefaultSite", "Subsite"."ID", CASE WHEN "Subsite"."ClassName" IS NOT NULL THEN "Subsite"."ClassName" ELSE 'SilverStripe\\Subsites\\Model\\Subsite' END AS "RecordClassName", "Subsite"."Title" FROM "Subsite" WHERE ("Subsite"."DefaultSite" = ?) ORDER BY "Subsite"."Title" ASC LIMIT 1 0.0006s

0006: SHOW FULL TABLES WHERE Table_Type != 'VIEW' 0.0017s

0007: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."URLSegment" = ?) AND ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0006s

0008: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."URLSegment" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0007s

0009: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0006s

0010: SELECT DISTINCT "Subsite"."ClassName", "Subsite"."LastEdited", "Subsite"."Created", "Subsite"."Title", "Subsite"."RedirectURL", "Subsite"."DefaultSite", "Subsite"."Theme", "Subsite"."Language", "Subsite"."IsPublic", "Subsite"."PageTypeBlacklist", "Subsite"."ID", CASE WHEN "Subsite"."ClassName" IS NOT NULL THEN "Subsite"."ClassName" ELSE 'SilverStripe\\Subsites\\Model\\Subsite' END AS "RecordClassName" FROM "Subsite" WHERE ("Subsite"."ID" = ?) ORDER BY "Subsite"."Title" ASC LIMIT 1 0.0005s

0011: SELECT DISTINCT "SiteConfig"."ClassName", "SiteConfig"."LastEdited", "SiteConfig"."Created", "SiteConfig"."Title", "SiteConfig"."Tagline", "SiteConfig"."CanViewType", "SiteConfig"."CanEditType", "SiteConfig"."CanCreateTopLevelType", "SiteConfig"."SubsiteID", "SiteConfig"."BrandID", "SiteConfig"."ID", CASE WHEN "SiteConfig"."ClassName" IS NOT NULL THEN "SiteConfig"."ClassName" ELSE 'SilverStripe\\SiteConfig\\SiteConfig' END AS "RecordClassName" FROM "SiteConfig" WHERE ("SiteConfig"."SubsiteID" IN (0)) LIMIT 1 0.0003s

0012: SELECT CASE WHEN EXISTS(SELECT * FROM "Subsite" ) THEN 1 ELSE 0 END 0.0006s

0013: SELECT DISTINCT "PublishDate" IS NULL AS "_SortColumn0", "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "BlogPost_Live"."PublishDate", "BlogPost_Live"."AuthorNames", "BlogPost_Live"."Summary", "BlogPost_Live"."ElementalAreaID", "BlogPost_Live"."FeaturedImageID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" LEFT JOIN "BlogPost_Live" ON "BlogPost_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) AND ("PublishDate" < '2024-12-28 07:38:23') ORDER BY "_SortColumn0" DESC, "BlogPost_Live"."PublishDate" DESC LIMIT 1 0.0028s

0014: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "Page_Live"."MenuSubtitle", "Page_Live"."MenuIcon", "Page_Live"."MenuStyle", "Page_Live"."BrandID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" INNER JOIN "BlogPost_Live" ON "SiteTree_Live"."ID" = "BlogPost_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?, ?, ?, ?, ?, ?, ?, ?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0005s

0015: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "Page_Live"."MenuSubtitle", "Page_Live"."MenuIcon", "Page_Live"."MenuStyle", "Page_Live"."BrandID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?, ?, ?, ?, ?, ?, ?, ?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0016: SELECT DISTINCT "Brand"."ClassName", "Brand"."LastEdited", "Brand"."Created", "Brand"."Title", "Brand"."Icon", "Brand"."Color", "Brand"."Pattern", "Brand"."ID", CASE WHEN "Brand"."ClassName" IS NOT NULL THEN "Brand"."ClassName" ELSE 'IGI\\Website\\Models\\Brand' END AS "RecordClassName" FROM "Brand" WHERE ("Brand"."ID" = ?) LIMIT 1 0.0021s

0017: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ShowInMenus" = ?) AND ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC 0.0031s

0018: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ParentID" <> "SiteTree_Live"."ID") AND ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."ShowInMenus" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC 0.0007s

0019: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0020: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ParentID" <> "SiteTree_Live"."ID") AND ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."ShowInMenus" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC 0.0005s

0021: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0022: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0023: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "Page_Live"."MenuSubtitle", "Page_Live"."MenuIcon", "Page_Live"."MenuStyle", "Page_Live"."BrandID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?, ?, ?, ?, ?, ?, ?, ?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0004s

0024: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "RedirectorPage_Live"."RedirectionType", "RedirectorPage_Live"."ExternalURL", "RedirectorPage_Live"."LinkToID", "RedirectorPage_Live"."LinkToFileID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "RedirectorPage_Live" ON "RedirectorPage_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.001s

0025: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "RedirectorPage_Live"."RedirectionType", "RedirectorPage_Live"."ExternalURL", "RedirectorPage_Live"."LinkToID", "RedirectorPage_Live"."LinkToFileID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "RedirectorPage_Live" ON "RedirectorPage_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0005s

0026: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ParentID" <> "SiteTree_Live"."ID") AND ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."ShowInMenus" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC 0.0005s

0027: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0004s

0028: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0029: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0030: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "Page_Live"."MenuSubtitle", "Page_Live"."MenuIcon", "Page_Live"."MenuStyle", "Page_Live"."BrandID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?, ?, ?, ?, ?, ?, ?, ?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0031: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "RedirectorPage_Live"."RedirectionType", "RedirectorPage_Live"."ExternalURL", "RedirectorPage_Live"."LinkToID", "RedirectorPage_Live"."LinkToFileID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "RedirectorPage_Live" ON "RedirectorPage_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0004s

0032: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "RedirectorPage_Live"."RedirectionType", "RedirectorPage_Live"."ExternalURL", "RedirectorPage_Live"."LinkToID", "RedirectorPage_Live"."LinkToFileID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "RedirectorPage_Live" ON "RedirectorPage_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0033: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "RedirectorPage_Live"."RedirectionType", "RedirectorPage_Live"."ExternalURL", "RedirectorPage_Live"."LinkToID", "RedirectorPage_Live"."LinkToFileID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "RedirectorPage_Live" ON "RedirectorPage_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0034: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" INNER JOIN "BlogPost_Live" ON "BlogPost_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ParentID" = ?) AND (("SiteTree_Live"."ID" != ? OR "SiteTree_Live"."ID" IS NULL)) AND ("SiteTree_Live"."ShowInMenus" = ?) AND ("PublishDate" < '2024-12-28 07:38:23') AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC 0.0011s

0035: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ParentID" <> "SiteTree_Live"."ID") AND ("SiteTree_Live"."ParentID" = ?) AND ("SiteTree_Live"."ShowInMenus" = ?) AND ("SiteTree_Live"."SubsiteID" IN (0)) ORDER BY "SiteTree_Live"."Sort" ASC 0.0007s

0036: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0005s

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0038: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0005s

0039: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0040: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "Page_Live"."MenuSubtitle", "Page_Live"."MenuIcon", "Page_Live"."MenuStyle", "Page_Live"."BrandID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName", "SiteTree_Live"."Sort" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" WHERE ("SiteTree_Live"."ID" = ?) AND ("SiteTree_Live"."ClassName" IN (?, ?, ?, ?, ?, ?, ?, ?)) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0003s

0041: SELECT DISTINCT "BlogCategory"."ClassName", "BlogCategory"."LastEdited", "BlogCategory"."Created", "BlogCategory"."Title", "BlogCategory"."URLSegment", "BlogCategory"."BlogID", "BlogCategory"."ID", CASE WHEN "BlogCategory"."ClassName" IS NOT NULL THEN "BlogCategory"."ClassName" ELSE 'SilverStripe\\Blog\\Model\\BlogCategory' END AS "RecordClassName" FROM "BlogCategory" INNER JOIN "BlogPost_Categories" ON "BlogPost_Categories"."BlogCategoryID" = "BlogCategory"."ID" WHERE ("BlogPost_Categories"."BlogPostID" = ?) 0.0041s

0042: SELECT DISTINCT count(DISTINCT "BlogCategory"."ID") AS "Count" FROM "BlogCategory" INNER JOIN "BlogPost_Categories" ON "BlogPost_Categories"."BlogCategoryID" = "BlogCategory"."ID" WHERE ("BlogPost_Categories"."BlogPostID" = ?) 0.0005s

0043: SELECT DISTINCT "Member"."ClassName", "Member"."LastEdited", "Member"."Created", "Member"."URLSegment", "Member"."BlogProfileSummary", "Member"."BlogProfileRole", "Member"."FirstName", "Member"."Surname", "Member"."Email", "Member"."TempIDHash", "Member"."TempIDExpired", "Member"."Password", "Member"."AutoLoginHash", "Member"."AutoLoginExpired", "Member"."PasswordEncryption", "Member"."Salt", "Member"."PasswordExpiry", "Member"."LockedOutUntil", "Member"."Locale", "Member"."FailedLoginCount", "Member"."BlogProfileImageID", "Member"."ID", CASE WHEN "Member"."ClassName" IS NOT NULL THEN "Member"."ClassName" ELSE 'SilverStripe\\Security\\Member' END AS "RecordClassName" FROM "Member" INNER JOIN "BlogPost_Authors" ON "BlogPost_Authors"."MemberID" = "Member"."ID" WHERE ("BlogPost_Authors"."BlogPostID" = ?) ORDER BY "Member"."Surname" ASC, "Member"."FirstName" ASC LIMIT 1 0.0025s

0044: SELECT DISTINCT "ElementalArea_Live"."ClassName", "ElementalArea_Live"."LastEdited", "ElementalArea_Live"."Created", "ElementalArea_Live"."Version", "ElementalArea_Live"."OwnerClassName", "ElementalArea_Live"."TopPageID", "ElementalArea_Live"."ID", CASE WHEN "ElementalArea_Live"."ClassName" IS NOT NULL THEN "ElementalArea_Live"."ClassName" ELSE 'DNADesign\\Elemental\\Models\\ElementalArea' END AS "RecordClassName" FROM "ElementalArea_Live" WHERE ("ElementalArea_Live"."ID" = ?) LIMIT 1 0.0025s

0045: SELECT DISTINCT "Element_Live"."ClassName", "Element_Live"."LastEdited", "Element_Live"."Created", "Element_Live"."Version", "Element_Live"."Title", "Element_Live"."ShowTitle", "Element_Live"."Sort", "Element_Live"."ExtraClass", "Element_Live"."Style", "Element_Live"."TopPageID", "Element_Live"."ParentID", "Element_Live"."ID", CASE WHEN "Element_Live"."ClassName" IS NOT NULL THEN "Element_Live"."ClassName" ELSE 'DNADesign\\Elemental\\Models\\BaseElement' END AS "RecordClassName" FROM "Element_Live" WHERE ("Element_Live"."ParentID" = ?) ORDER BY "Element_Live"."Sort" ASC 0.015s

0046: SELECT DISTINCT "ElementalArea_Live"."ClassName", "ElementalArea_Live"."LastEdited", "ElementalArea_Live"."Created", "ElementalArea_Live"."Version", "ElementalArea_Live"."OwnerClassName", "ElementalArea_Live"."TopPageID", "ElementalArea_Live"."ID", CASE WHEN "ElementalArea_Live"."ClassName" IS NOT NULL THEN "ElementalArea_Live"."ClassName" ELSE 'DNADesign\\Elemental\\Models\\ElementalArea' END AS "RecordClassName" FROM "ElementalArea_Live" WHERE ("ElementalArea_Live"."ID" = ?) LIMIT 1 0.0003s

0047: SELECT DISTINCT "PublishDate" IS NULL AS "_SortColumn0", "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "Page_Live"."MenuSubtitle", "Page_Live"."MenuIcon", "Page_Live"."MenuStyle", "Page_Live"."BrandID", "BlogPost_Live"."PublishDate", "BlogPost_Live"."AuthorNames", "BlogPost_Live"."Summary", "BlogPost_Live"."ElementalAreaID", "BlogPost_Live"."FeaturedImageID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" LEFT JOIN "Page_Live" ON "Page_Live"."ID" = "SiteTree_Live"."ID" LEFT JOIN "BlogPost_Live" ON "BlogPost_Live"."ID" = "SiteTree_Live"."ID" WHERE ("BlogPost_Live"."ElementalAreaID" = ?) AND ("SiteTree_Live"."ClassName" = ?) AND ("SiteTree_Live"."ClassName" IN (?)) AND ("SiteTree_Live"."SubsiteID" IN (0)) AND ("PublishDate" < '2024-12-28 07:38:23') ORDER BY "_SortColumn0" DESC, "BlogPost_Live"."PublishDate" DESC LIMIT 1 0.0009s

0048: SELECT DISTINCT "SiteTree_Live"."ClassName", "SiteTree_Live"."LastEdited", "SiteTree_Live"."Created", "SiteTree_Live"."Priority", "SiteTree_Live"."CanViewType", "SiteTree_Live"."CanEditType", "SiteTree_Live"."Version", "SiteTree_Live"."URLSegment", "SiteTree_Live"."Title", "SiteTree_Live"."MenuTitle", "SiteTree_Live"."Content", "SiteTree_Live"."MetaDescription", "SiteTree_Live"."ExtraMeta", "SiteTree_Live"."ShowInMenus", "SiteTree_Live"."ShowInSearch", "SiteTree_Live"."Sort", "SiteTree_Live"."HasBrokenFile", "SiteTree_Live"."HasBrokenLink", "SiteTree_Live"."ReportClass", "SiteTree_Live"."SubsiteID", "SiteTree_Live"."ParentID", "SiteTree_Live"."ID", CASE WHEN "SiteTree_Live"."ClassName" IS NOT NULL THEN "SiteTree_Live"."ClassName" ELSE 'SilverStripe\\CMS\\Model\\SiteTree' END AS "RecordClassName" FROM "SiteTree_Live" WHERE ("SiteTree_Live"."ID" = ?) ORDER BY "SiteTree_Live"."Sort" ASC LIMIT 1 0.0026s

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0051: SELECT DISTINCT "Element_Live"."ClassName", "Element_Live"."LastEdited", "Element_Live"."Created", "ElementContent_Live"."HTML", "Element_Live"."ID", CASE WHEN "Element_Live"."ClassName" IS NOT NULL THEN "Element_Live"."ClassName" ELSE 'DNADesign\\Elemental\\Models\\BaseElement' END AS "RecordClassName", "Element_Live"."Sort" FROM "Element_Live" LEFT JOIN "ElementContent_Live" ON "ElementContent_Live"."ID" = "Element_Live"."ID" WHERE ("Element_Live"."ID" = ?) AND ("Element_Live"."ClassName" IN (?)) ORDER BY "Element_Live"."Sort" ASC LIMIT 1 0.0156s

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Source-characteristic information preserved in hopane carbon number composition » IGI Ltd.

Source-characteristic information preserved in hopane carbon number composition

by Paul Farrimond

The hopane and sterane biomarkers are among the most extensively used compounds in petroleum geochemistry.  Whilst the various diagenetic reactions that convert biologically-derived sterol lipids to sterane biomarkers during sediment burial were well established back in the 1980’s (Mackenzie et al., 1982), the diagenetic pathways to hopane biomarkers are very poorly understood.  This is perhaps not surprising, as (unlike for sterols and steranes) the biological precursors of hopanes were not identified until many years after the discovery of the hopanes themselves (Ourisson et al., 1979).  Furthermore, these biohopanoids are complex functionalized lipids that are difficult to analyze; only relatively recently have methods been devised to allow their compositions to be determined in bacteria and modern sedimentary environments (Talbot & Farrimond, 2007; Talbot et al., 2007).

 

PF Jan 2017 1

Figure 1: Generalized structures of the hopane biomarkers and their biological precursors, the bacteriohopanepolyols. (X, Y & Z represent the sites of various functional groups, often –OH; R represents a hydrocarbon chain of variable length).

 

The highly functionalized side chains are extensively altered during sediment burial, resulting in the formation of hopane biomarkers with a range of carbon numbers (mainly C27 to C35) depending on how much of the side chain is preserved.  The carbon number distribution of the resulting hopanes is likely to be influenced strongly by both the composition of the original biohopanoid precursors and the environmental and diagenetic conditions.

Abundance of C30 hopane

It has long been recognized that lacustrine-sourced oils often contain a high proportion of C30 hopane compared to the C31-C35 homologues (Fig.2).  Development of techniques to determine the precursor biohopanoids in modern sediments has shown that lake sediments are relatively enriched in compounds with six functional groups on the side chain (Farrimond et al., 2000), and it is likely that this leads to preferential cleavage of the chain between the Y and Z groups (Fig.1), giving increased proportions of C30 hopane.

Abundance of C35 hopanes

Source rocks with a high proportion of organic sulphur tend to produce oils with prominent C35 hopanes; such source rocks are typically deposited in marine anoxic (sulphidic) and/or carbonate settings.  It seems that binding of precursor biohopanoids into the kerogen by relatively weak carbon-sulphur (and sulphur-sulphur) bonds favours the preservation of the intact side chain, resulting in preferred liberation of C35 hopanes (Fig.2).

PF Jan 2017 2

Figure 2: M/z 191 mass chromatograms showing a lacustrine-sourced oil (left) with a high relative abundance of C30 hopane compared with the extended (C31-C35) homologues, and (right) a sulphur-rich sample with abundant C35 hopanes.

 

Abundance of C32, C33 or C34 hopanes

Some oils and source rocks have hopane distributions with enhanced relative amounts of the C32, C33 or C34 homologue (e.g. Moldowan et al., 1992).  Although useful in correlations, and often shown on carbon number “profile” plots (Fig.3), the origin and significance of these unusual distributions are not known.  Specific precursor biohopanoids contributing to the source rock are the most likely cause.

PF Jan 2017 3

Figure 3: Example hopane carbon number “profile” plot comparing the hopane fingerprints of three oils (produced using IGI’s p:IGI software).

 

Further information on the origin of hopane biomarkers and their use in petroleum geochemistry can be found in IGI’s ig.NET software, together with details of many other biomarker applications.

 

References:

Farrimond P., Head I.M. & Innes H.E. (2000). Environmental influence on the biohopanoid composition of recent sediments. Geochimica et Cosmochimica Acta64, 2985-2992.

Mackenzie A.S., Brassell S.C., Eglinton G. & Maxwell J.R. (1982). Chemical fossils: The geological fate of steroids. Science217, 491-505.

Moldowan  J. M., Lee C.Y., Sundararaman P., Salvatori T., Alajbeg A., Gjukić B., Demaison G.J., Slougui N.-E. & Watt D.S. (1992). Source correlation and maturity assessment of select oils and rocks from the Central Adriatic Basin (Italy and Yugoslavia). In: Biological Markers in Sediments and Petroleum (J. M. Moldowan, P. Albrecht and R. P. Philp, eds.), New Jersey, Prentice Hall, 370-471.

Ourisson G., Albrecht P. & Rohmer M. (1979). The hopanoids: Palaeochemistry and biochemistry of a group of natural products. Pure & Applied Chemistry51, 709-729.

Talbot H.M. & Farrimond P. (2007).  Bacterial populations recorded in diverse sedimentary biohopanoid distributions. Org. Geochem.38, 1212-1225.

Talbot H.M., Rohmer M. & Farrimond P. (2007). Rapid structural elucidation of composite bacterial hopanoids by atmospheric pressure chemical ionisation liquid chromatography/ion trap mass spectrometry. Rapid Communications in Mass Spectrometry21, 880-892.